Site-Selective C-H Functionalization of Indoles: Studies towards C-C and C-N Bond Formation

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creativework.keywordsKeywordsen
dc.contributor.authorBanerjee, Sonbidya
dc.date.accessioned2024-05-31T09:54:33Z
dc.date.available2024-05-31T09:54:33Z
dc.date.issued2024
dc.descriptionSupervisor: Punniyamurthy, Ten_US
dc.description.abstractThe thesis is structured into four chapters. The first chapter describes a Ru-catalyzed regioselective C-N bond formation of indolines and carbazole with acyl azides via C7(sp2)-H activation followed by an intramolecular C-N bond formation for the construction of 7- aminoindoline and 1-aminocarbazole scaffolds. The second chapter deals with Cu-catalyzed C7- selective C-H/N-H cross-dehydrogenative coupling of indolines and azaindoles with sulfoximines. The third chapter demonstrates a Rh-catalyzed site-selective C7 and C6 dual C-H functionalization of indolines expending 7-azabenzonorbornaiene for the formation of functionalized pyrrolocarbazoles. The fourth chapter focuses on Pd-catalyzed weak-coordination facilitated C4- selective redox-neutral nitration of indoles with tert-butyl nitrite under aerobic oxidation catalysis.en_US
dc.identifier.otherROLL NO.176122109
dc.identifier.urihttps://gyan.iitg.ac.in/handle/123456789/2626
dc.language.isoenen_US
dc.relation.ispartofseriesTH-3372;
dc.subjectIndole Functionalizationen_US
dc.subjectCarbazoleen_US
dc.subjectSulfoximineen_US
dc.subjectC7-Amidationen_US
dc.subjectC7-Aminationen_US
dc.subjectC7 and C6-Dual Functionalizationen_US
dc.subjectPyrrolocarbazole formationen_US
dc.subjectC4-Nitrationen_US
dc.subjectMechanistic Investigationsen_US
dc.subjectBroad Substrate Scopeen_US
dc.subjectPost-synthetic Utilitiesen_US
dc.titleSite-Selective C-H Functionalization of Indoles: Studies towards C-C and C-N Bond Formationen_US
dc.typeThesisen_US
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