Designing of hetero-bimetallic cyclic trinuclear, polymeric chains, and linear trinuclear from Cu(II), Fe(III), and Co(III) complexes using alkali, alkaline, and transition metal ions

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creativework.keywordsKeywordsen
dc.contributor.authorChanreingam, L
dc.date.accessioned2024-05-29T11:42:25Z
dc.date.available2024-05-29T11:42:25Z
dc.date.issued2024
dc.descriptionSupervisor: Ray, Manabendra
dc.description.abstractA simple ligand, which is chiral and flexible, was used to synthesize Cu(II) complexes such that the resulting complex can act as a chiral host and is flexible enough to obtain a secondary coordination sphere. Cu(II) bis complex, when reacted with K+ ion, forms a cyclic trinuclear, which resembles an inorganic crown ether. In this process, the trans-oriented Cu(II) bis complex was converted to a cis-oriented complex. An excess of [18] crown-6 was added, and the K+ was removed from the assembly, thereby obtaining a cis-oriented Cu(II) monomer. The cis-oriented disassembled Cu(II) monomer, when reacted with K+, forms back the assembly.
dc.identifier.otherROLL NO.186122009
dc.identifier.urihttps://gyan.iitg.ac.in/handle/123456789/2618
dc.language.isoen
dc.relation.ispartofseriesTH-3355
dc.titleDesigning of hetero-bimetallic cyclic trinuclear, polymeric chains, and linear trinuclear from Cu(II), Fe(III), and Co(III) complexes using alkali, alkaline, and transition metal ions
dc.typeThesis
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