Designing of hetero-bimetallic cyclic trinuclear, polymeric chains, and linear trinuclear from Cu(II), Fe(III), and Co(III) complexes using alkali, alkaline, and transition metal ions
| creativework.keywords | Keywords | en |
| dc.contributor.author | Chanreingam, L | |
| dc.date.accessioned | 2024-05-29T11:42:25Z | |
| dc.date.available | 2024-05-29T11:42:25Z | |
| dc.date.issued | 2024 | |
| dc.description | Supervisor: Ray, Manabendra | en_US |
| dc.description.abstract | A simple ligand, which is chiral and flexible, was used to synthesize Cu(II) complexes such that the resulting complex can act as a chiral host and is flexible enough to obtain a secondary coordination sphere. Cu(II) bis complex, when reacted with K+ ion, forms a cyclic trinuclear, which resembles an inorganic crown ether. In this process, the trans-oriented Cu(II) bis complex was converted to a cis-oriented complex. An excess of [18] crown-6 was added, and the K+ was removed from the assembly, thereby obtaining a cis-oriented Cu(II) monomer. The cis-oriented disassembled Cu(II) monomer, when reacted with K+, forms back the assembly. | en_US |
| dc.identifier.other | ROLL NO.186122009 | |
| dc.identifier.uri | https://gyan.iitg.ac.in/handle/123456789/2618 | |
| dc.language.iso | en | en_US |
| dc.relation.ispartofseries | TH-3355; | |
| dc.subject | Heterobimetallic | en_US |
| dc.subject | Secondary Cations | en_US |
| dc.subject | Protonation | en_US |
| dc.subject | and Inert Complex | en_US |
| dc.title | Designing of hetero-bimetallic cyclic trinuclear, polymeric chains, and linear trinuclear from Cu(II), Fe(III), and Co(III) complexes using alkali, alkaline, and transition metal ions | en_US |
| dc.type | Thesis | en_US |
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