Study of Asymmetric Cyanohydrin and Sulfoxidation Reactions,and Fluorometric Recognition of Zn2+ and Optically Active2-Substituted Pyridines and Fluorometric Recognition of Zn2+ and Optically Active

Loading...
Thumbnail Image

Date

Journal Title

Journal ISSN

Volume Title

Publisher

Abstract

The thesis contains five chapters. The first chapter describes the synthesis of chiral mainchain polymers bonded with (R,R)-salen and 1,4-dioctyloxybenzene as alternate segments. The chapter two deals with the titanium polymer complex formation and its application for 1,2-addition of trimethylsilyl cyanide (TMSCN) to aldehydes. The third chapter focuses on chiral titanium-catalyzed asymmetric sulfoxidation with aqueous hydrogen peroxide. The fourth and fifth chapters deal with the use of the polymers as chemosensor for cascade Zn2+ detection and chiral recognition toward optically active 2-substituted pyridines.

Description

Supervisor: T. Punniyamourthy

Keywords

Citation

Endorsement

Review

Supplemented By

Referenced By