Studies Towards Weak Chelation Assisted Regioselective C-H Activation/C-C Bond Formation: Exploration to Functionalized Heterocycles

Loading...
Thumbnail Image

Date

Journal Title

Journal ISSN

Volume Title

Publisher

Abstract

The thesis is divided into four chapters. The first chapter describes the recent advances on transition-metal (TM)-catalyzed weak chelation assisted regioselective C-H functionalization and annulation reactions. The second chapter deals with the weak chelation-guided Rh-catalyzed C4-H alkylation of indoles with cyclopropanols via merging C-H/C-C bond activation. The third chapter demonstrates a biorelevant weakly coordinating directing group (DG) assisted arene C-H alkenylation with cyclopropanols. The fourth chapter focuses on weak chelation assisted oxidative C-H/C-H coupling/annulation cascade of aryl/vinyl phosphonic acid monoesters and benzothiophenes to construct benzothieno-fused oxaphosphacycles.

Description

Supervisor: Punniyamurthy, Tharmalingam

Keywords

Citation

Endorsement

Review

Supplemented By

Referenced By