Ghorai, Samir2015-09-232023-10-192015-09-232023-10-192014ROLL NO. 11612213https://gyan.iitg.ac.in/handle/123456789/557Supervisor: Chandan MukherjeeGeneral Introduction and Motivation: Widespread naturally occurring enzymatic reactions are proceeded through a transient species consis of organic ?-radical mainly, tyrosine radical-or prorphyrin radical containing metal complexes, known as metalloenzymes, e.g...enCHEMISTRYGeometrical and Substitutional Influences on the Electronic Structure and the Reactivity of First--Row Transition MetalThesis