Anthracene and Aminothiazole Based Organo-Cations Guiding Ionic-Cocrystals, Hydrates of Pyridinedicarboxylic Acids and Selected Metal Complexes

creativework.keywordsKeywordsen
dc.contributor.authorSingh, Abhay Pratap
dc.date.accessioned2025-05-16T05:26:02Z
dc.date.available2025-05-16T05:26:02Z
dc.date.issued2025
dc.descriptionSupervisor: Baruah, Jubaraj Bikash
dc.description.abstractThe research presented in this thesis is based on the synthesis, structural characterization, and self-assemblies of salts, ionic-cocrystals and hydrates. Series of 2,6- and 3,5-pyridinedicarboxylate ionic-cocrystals were investigated to show newness in their compositions by complete or partial deprotonations. Different multi-component cocrystals with novel photoluminescence properties are demonstrated in the thesis. Multiple numbers of hydrates from different anionic cobalt(II), copper(II), and zinc(II) pyridinedicarboxylate complexes possessing anthracene-based organo-cations and their interconversions are depicted. The contribution highlights diverse non-covalent assemblies formed through weak interactions such as hydrogen bonds, halogen bonds, π-stacking, and chelate-chelate interactions. The study was extended to zinc(II) pyridinedicarboxylate complexes containing sulfathiazolium cations to demonstrate variations in the bioavailability of a drug molecule derived from the same components in each case but with different compositions. This thesis has opened scopes for newer avenues to explore assemblies of ionic-cocrystals as well as solvated metal complexes to observe new properties and transformations among the ionic forms within an assembly by stimuli such as concentration gradient or additives.
dc.identifier.otherROLL NO.196122001
dc.identifier.urihttps://gyan.iitg.ac.in/handle/123456789/2903
dc.language.isoen
dc.relation.ispartofseriesTH-3622
dc.titleAnthracene and Aminothiazole Based Organo-Cations Guiding Ionic-Cocrystals, Hydrates of Pyridinedicarboxylic Acids and Selected Metal Complexes
dc.typeThesis

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