Anthracene and Aminothiazole Based Organo-Cations Guiding Ionic-Cocrystals, Hydrates of Pyridinedicarboxylic Acids and Selected Metal Complexes
creativework.keywords | Keywords | en |
dc.contributor.author | Singh, Abhay Pratap | |
dc.date.accessioned | 2025-05-16T05:26:02Z | |
dc.date.available | 2025-05-16T05:26:02Z | |
dc.date.issued | 2025 | |
dc.description | Supervisor: Baruah, Jubaraj Bikash | |
dc.description.abstract | The research presented in this thesis is based on the synthesis, structural characterization, and self-assemblies of salts, ionic-cocrystals and hydrates. Series of 2,6- and 3,5-pyridinedicarboxylate ionic-cocrystals were investigated to show newness in their compositions by complete or partial deprotonations. Different multi-component cocrystals with novel photoluminescence properties are demonstrated in the thesis. Multiple numbers of hydrates from different anionic cobalt(II), copper(II), and zinc(II) pyridinedicarboxylate complexes possessing anthracene-based organo-cations and their interconversions are depicted. The contribution highlights diverse non-covalent assemblies formed through weak interactions such as hydrogen bonds, halogen bonds, π-stacking, and chelate-chelate interactions. The study was extended to zinc(II) pyridinedicarboxylate complexes containing sulfathiazolium cations to demonstrate variations in the bioavailability of a drug molecule derived from the same components in each case but with different compositions. This thesis has opened scopes for newer avenues to explore assemblies of ionic-cocrystals as well as solvated metal complexes to observe new properties and transformations among the ionic forms within an assembly by stimuli such as concentration gradient or additives. | |
dc.identifier.other | ROLL NO.196122001 | |
dc.identifier.uri | https://gyan.iitg.ac.in/handle/123456789/2903 | |
dc.language.iso | en | |
dc.relation.ispartofseries | TH-3622 | |
dc.title | Anthracene and Aminothiazole Based Organo-Cations Guiding Ionic-Cocrystals, Hydrates of Pyridinedicarboxylic Acids and Selected Metal Complexes | |
dc.type | Thesis |
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