Auxiliary-Assisted C-H Functionalization: Exploring the Realm of C-C and C-Heteroatom Bond Formation
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Date
2024
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Abstract
The thesis is segmented into four chapters. The initial chapter delineates a Rh-Catalyzed Tandem C-C/C-N bond formation of quinoxalines with alkynes leading to heterocyclic ammonium salts. The second chapter explores the Pd-Catalyzed sp3 C-H alkoxycarbonylation of 8-methylquinolines using Mo(CO)6 as a CO surrogate. The third chapter showcases the Rh-catalyzed alkenylation of aryl 2-pyridyl ethers with vinyl acetate via sp2 C-H activation. Lastly, the fourth chapter delves into on Ru-catalyzed site selective acetoxylation of aryl 2-pyridyl ethers exploiting vinyl acetate as acetoxylating agent
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Supervisor: Punniyamurthy, T
Keywords
C-H Activation/Functionalization, Heterocycles, Alkoxycarbonylation, Alkenylation, Acetoxylation