Browsing by Author "Chanreingam, L"
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Item Designing of hetero-bimetallic cyclic trinuclear, polymeric chains, and linear trinuclear from Cu(II), Fe(III), and Co(III) complexes using alkali, alkaline, and transition metal ions(2024) Chanreingam, LA simple ligand, which is chiral and flexible, was used to synthesize Cu(II) complexes such that the resulting complex can act as a chiral host and is flexible enough to obtain a secondary coordination sphere. Cu(II) bis complex, when reacted with K+ ion, forms a cyclic trinuclear, which resembles an inorganic crown ether. In this process, the trans-oriented Cu(II) bis complex was converted to a cis-oriented complex. An excess of [18] crown-6 was added, and the K+ was removed from the assembly, thereby obtaining a cis-oriented Cu(II) monomer. The cis-oriented disassembled Cu(II) monomer, when reacted with K+, forms back the assembly.