Numerical modelling of non-equilibrium reactive transport in acid mine drainage

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dc.contributor.author Someswaran, R
dc.date.accessioned 2021-01-07T05:33:53Z
dc.date.available 2021-01-07T05:33:53Z
dc.date.issued 2019
dc.identifier.other ROLL NO.09610411
dc.identifier.uri http://gyan.iitg.ernet.in/handle/123456789/1783
dc.description Supervisor: Suresh A. Kartha en_US
dc.description.abstract The conventional computational models on solute transport use the simple advection diffusion equation to simulate the contaminant movement in subsurface, however, the equation has some limitations since some processes cannot be simulated; like occurrence of non-equilibrium in mass distribution during transport through the porous medium. This happens due to the presence of stagnant (immobile) water at the disconnected pores (dead end pores) of porous medium, where the velocity of the stagnant water is negligible with respect to mobile water. Mass transfer happens due to the physical nature of soil is defined as physical non-equilibrium. Mass transfer between mobile and immobile water region retards the contaminant transport and the immobile water zones may act as sinks/sources of contaminants and it can cause non-ideal conditions in solute distribution and early arrival of solutes at the downstream. Contaminants like Acid Mine Drainage (AMD), effluent acidic water that drains from the mining sites, etc. are reactive in nature and it will be interesting to study the transport of AMD in the presence of non-equilibrium mass transfer. Pyrite oxidation reaction adds acidity to the surface water that leads to the dissolution of heavy metals and its transport towards groundwater zone. This research conceptualizes the liquid zones in the porous subsurface medium to have mobile and immobile zones. In addition, the study emphasizes the use of mass transfer of water as well as contaminants simultaneously between the mobile and immobile regions that are rarely studied. The open source FEMWATER model, developed by USEPA, was modified to accommodate liquid mass transfer between the mobile and immobile regions and the transport module, 3DLEWASTE, was modified to handle the non-equilibrium solute mass transport and an ion-exchange reaction is newly added to the source code of the model. en_US
dc.language.iso en en_US
dc.relation.ispartofseries TH-2330;
dc.subject CIVIL ENGINEERING en_US
dc.title Numerical modelling of non-equilibrium reactive transport in acid mine drainage en_US
dc.type Thesis en_US


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